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The shape change associated with a { 1121 } twin having a much larger magnitude of twinning shear is shown in Fig. 8]. Under compression loading parallel to the caxis { 1122 } twins are activated allowing a contraction along the c-axis (Fig. 8]. 14]. Increasing concentrations of solute atoms in α titanium, such as oxygen or aluminum, suppress the occurrence of twinning. 10]. Fig. 8. 5 Phase Diagrams 23 Fig. 9. 3. 5 Phase Diagrams Alloying elements in titanium are usually classified into α or β stabilizing additions depending on whether they increase or decrease the α/β transformation temperature of 882°C of pure titanium.

30. Among the other important alloying elements belonging to this group, V and Sn are close to Al, and Nb lies in between Al and Mo. Among the group of fast diffusing elements, Fe is shown as an example in Fig. 30. Ni is even slightly faster, whereas Cr and Mn fall in between Fe and the β-Ti self-diffusion line. 34], is taken for Fig. 34], the slope (activation energy) of the lower set of curves seems to be too high. 34], and the line shown in Fig. 30 seems to be well established. Only a limited number of diffusivity measurements for aluminum in α titanium exists and, apart from the scatter, most of these data lie close to the oxygen line in Fig.

An example of such a microstructure which was obtained by slow cooling from the β phase field is shown in Fig. 17 for the Ti-6Al-4V alloy. In such slowly cooled material, the size of the α colonies can be as large as half of the β grain size. a b Fig. 17. Lamellar α+β microstructure in Ti-6Al-4V slowly cooled from the β phase field: (a) LM (b) TEM The crystallographic relationship between α and β plates within a colony is schematically shown in Fig. 18. It can be seen that the Burgers relationship ( 110 )β || ( 0002 )α and [ 1 1 1 ]β || [ 1120 ]α is strictly obeyed and that the flat surface of the α plates is parallel to the ( 1 100 ) plane of the α phase and parallel to the ( 1 12 ) plane of the β phase.

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